---[ end Kernel panic - not syncing: VFS: Unable to mount root fs on unknown-block(0,0) ]---
Now I am trying to resolve this issue by using a Linux Mint live environment. Read this and after mounting the root partition and checking out the kernel configuration, I see that support for Ext4 is built into the kernel itself. So, I moved to the next thing, which was to check if the block-ids were somehow messed up, I think there's no issue over there either, but as I am a newb, here's grub.cfg, fdisk -l and the output of blkid is as follows:
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/dev/nvme0n1p3: UUID="36cbcca8-5d46-492b-a319-8790b027851f" BLOCK_SIZE="4096" TYPE="ext4" PARTUUID="5b03a4a8-df5f-6c42-a5ea-6bc03cc3909e"
/dev/nvme0n1p1: UUID="8AFC-79D4" BLOCK_SIZE="512" TYPE="vfat" PARTUUID="7d0b4168-639e-0a4e-ba5b-ca6f2ec12775"
/dev/nvme0n1p2: UUID="38244e92-59dc-4aed-baef-09a28c23fa49" TYPE="swap" PARTUUID="a8821742-0bec-8a4b-bde9-5735c0dc5494"
/dev/sdb1: LABEL="Ventoy" UUID="1712-9171" BLOCK_SIZE="512" TYPE="exfat" PTTYPE="dos" PARTUUID="391ba92f-01"
/dev/loop0: TYPE="squashfs"
/dev/dm-0: BLOCK_SIZE="2048" UUID="2022-12-17-20-57-31-00" LABEL="Linux Mint 21.1 MATE 64-bit" TYPE="iso9660" PTUUID="3f309abc-7fd8-484e-ad0c-f7cac0efb2ed" PTTYPE="gpt"
/dev/sda: UUID="ce6da296-4ea1-458f-8764-11a3f7484991" BLOCK_SIZE="4096" TYPE="ext4"

